Samuel Chukwueze was again on the score sheet with a stoppage time effort as Villarreal won 3-1 at Real Sociedad.
Chukwueze made it 3-1 for his team deep into stoppage time.
It was his fifth goal since his comeback from long-term injuries.
Villarreal have now climbed to 10th on the table with 22 points from 17 matches.
In the Spanish lower league, Super Eagles defender Kenneth Omeruo was also on target.
Omeruo scored in the second half as CD Leganes won 2-0 at Malaga.
Leganes are now 15th in the standings after 21 matches.